The syn- and anti-isoprenoid units 1a and 5a have been prepared in good yields from the corresponding cis- and trans-2,6-dimethylcyclooctanones 2a and 6a obtained, in turn, through skeletal rearrangement of the bicyclo[3.3.1]nonanic precursor 8a. The 2a/6a ratio ranges from 1:1 to 4:1 depending on the reaction conditions.

GAMBACORTA A, TURCHETTA S, FARAH ME, & BOTTA M (1992). BICYCLO[3.3.1]NONANE APPROACH TO POLYMETHYL ALTERNATING SYSTEMS - THE SYN-1,5-DIMETHYL SYSTEMS AND ANTI-1,5-DIMETHYL SYSTEMS. GAZZETTA CHIMICA ITALIANA, 122(12), 527-529.

BICYCLO[3.3.1]NONANE APPROACH TO POLYMETHYL ALTERNATING SYSTEMS - THE SYN-1,5-DIMETHYL SYSTEMS AND ANTI-1,5-DIMETHYL SYSTEMS

GAMBACORTA, Augusto;
1992

Abstract

The syn- and anti-isoprenoid units 1a and 5a have been prepared in good yields from the corresponding cis- and trans-2,6-dimethylcyclooctanones 2a and 6a obtained, in turn, through skeletal rearrangement of the bicyclo[3.3.1]nonanic precursor 8a. The 2a/6a ratio ranges from 1:1 to 4:1 depending on the reaction conditions.
GAMBACORTA A, TURCHETTA S, FARAH ME, & BOTTA M (1992). BICYCLO[3.3.1]NONANE APPROACH TO POLYMETHYL ALTERNATING SYSTEMS - THE SYN-1,5-DIMETHYL SYSTEMS AND ANTI-1,5-DIMETHYL SYSTEMS. GAZZETTA CHIMICA ITALIANA, 122(12), 527-529.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11590/115946
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