Gas phase near-edge X-ray absorption fine structure spectra of phenylacetylene (PA, C6H5-C=CH) have been recorded at the carbon K-edge. The experimental data have been interpreted with the help of ab initio calculations: both the ionisation potentials for the Cls electrons and the theoretical C K-edge absorption spectra have been calculated for all the six inequivalent carbon atoms of PA. A good agreement is observed between experimental and theoretical data, allowing a detailed attribution of the various features in the measured spectrum

Carravetta, V., Polzonetti, G., Iucci, G., Russo, M.v., Paolucci, G., Barnaba, M. (1998). High resolution NEXAFS spectroscopy study of gas-phase phenylacetylene: experiment and theory. CHEMICAL PHYSICS LETTERS, 288, 37-46 [10.1016/S0009-2614(98)00143-2].

High resolution NEXAFS spectroscopy study of gas-phase phenylacetylene: experiment and theory

IUCCI, GIOVANNA;
1998-01-01

Abstract

Gas phase near-edge X-ray absorption fine structure spectra of phenylacetylene (PA, C6H5-C=CH) have been recorded at the carbon K-edge. The experimental data have been interpreted with the help of ab initio calculations: both the ionisation potentials for the Cls electrons and the theoretical C K-edge absorption spectra have been calculated for all the six inequivalent carbon atoms of PA. A good agreement is observed between experimental and theoretical data, allowing a detailed attribution of the various features in the measured spectrum
1998
Carravetta, V., Polzonetti, G., Iucci, G., Russo, M.v., Paolucci, G., Barnaba, M. (1998). High resolution NEXAFS spectroscopy study of gas-phase phenylacetylene: experiment and theory. CHEMICAL PHYSICS LETTERS, 288, 37-46 [10.1016/S0009-2614(98)00143-2].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11590/116574
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