Solvent- and supporting electrolyte-free electrolysis in a two-compartment cell proved to be effective for the direct electroactivation of C-H acid-containing compounds vs. catalytic addition processes. Michael adducts (including quaternary carbon centres) and 2-nitroalkanols were obtained in very good yields and selectivity on application of a catalytic amount of electricity under galvanostatic conditions.

Caruso, T., Feroci, M., Inesi, A., Orsini, M., Scettri, A., Palombi, L. (2006). “Electrochemically induced addition reactions in the absence of solvent and supporting electrolyte”. ADVANCED SYNTHESIS & CATALYSIS, 348, 1942-1947.

“Electrochemically induced addition reactions in the absence of solvent and supporting electrolyte”

ORSINI, MONICA;
2006-01-01

Abstract

Solvent- and supporting electrolyte-free electrolysis in a two-compartment cell proved to be effective for the direct electroactivation of C-H acid-containing compounds vs. catalytic addition processes. Michael adducts (including quaternary carbon centres) and 2-nitroalkanols were obtained in very good yields and selectivity on application of a catalytic amount of electricity under galvanostatic conditions.
Caruso, T., Feroci, M., Inesi, A., Orsini, M., Scettri, A., Palombi, L. (2006). “Electrochemically induced addition reactions in the absence of solvent and supporting electrolyte”. ADVANCED SYNTHESIS & CATALYSIS, 348, 1942-1947.
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11590/124127
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