Chiral 2-phenyl succinic ester derivatives have been obtained under mild conditions, in short times and with satisfactory yields by electrochemical reduction of chiral cinnamic acid derivatives under a CO2 atmosphere. When 4R-(diphenylmethyl)-oxazolidin-2-one was used as a chiral auxiliary the two diastereoisomers could be easily separated by. ash chromatography and the R-isomer was obtained as major product.

Orsini, M., Feroci, M., Sotgiu, G., Inesi, A. (2005). Stereoselective electrochemical carboxylation: 2-phenylsuccinates from chiral cinnamic acid derivatives. ORGANIC & BIOMOLECULAR CHEMISTRY, 3, 1202-1208.

Stereoselective electrochemical carboxylation: 2-phenylsuccinates from chiral cinnamic acid derivatives

ORSINI, MONICA;SOTGIU, Giovanni;
2005-01-01

Abstract

Chiral 2-phenyl succinic ester derivatives have been obtained under mild conditions, in short times and with satisfactory yields by electrochemical reduction of chiral cinnamic acid derivatives under a CO2 atmosphere. When 4R-(diphenylmethyl)-oxazolidin-2-one was used as a chiral auxiliary the two diastereoisomers could be easily separated by. ash chromatography and the R-isomer was obtained as major product.
2005
Orsini, M., Feroci, M., Sotgiu, G., Inesi, A. (2005). Stereoselective electrochemical carboxylation: 2-phenylsuccinates from chiral cinnamic acid derivatives. ORGANIC & BIOMOLECULAR CHEMISTRY, 3, 1202-1208.
File in questo prodotto:
Non ci sono file associati a questo prodotto.

I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.

Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11590/124145
Citazioni
  • ???jsp.display-item.citation.pmc??? ND
  • Scopus 31
  • ???jsp.display-item.citation.isi??? 30
social impact