The title compound is the only product in the intramolecular aldol condensation of dione 3, obtained in turn from the bicyclo[3.3.1]nonanic hydroxyketal 5. This behaviour is at variance with force field calculations.
Gambacorta, A., Turchetta, S., Stefanelli, S., Botta, M. (1991). BICYCLO[3.3.1]NONANES AS SYNTHETIC INTERMEDIATES - SYNTHESIS OF 1-HYDROXY-ANTI-8-ACETYLBICYCLO[4.2.2]DECANE. TETRAHEDRON LETTERS, 32(46), 6805-6808 [10.1016/S0040-4039(00)93608-6].
BICYCLO[3.3.1]NONANES AS SYNTHETIC INTERMEDIATES - SYNTHESIS OF 1-HYDROXY-ANTI-8-ACETYLBICYCLO[4.2.2]DECANE
GAMBACORTA, Augusto;
1991-01-01
Abstract
The title compound is the only product in the intramolecular aldol condensation of dione 3, obtained in turn from the bicyclo[3.3.1]nonanic hydroxyketal 5. This behaviour is at variance with force field calculations.File in questo prodotto:
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