Substituted cis-1-formyl (or acetyl) bicyclo[3.3.0]octanes are stereospecifically obtained in high yield by a base-catalyzed rearrangement of readily accessible substituted 1-chloro-9-hydroxy (or acetoxy) bicyclo[3.3.1] nonanes.
Gambacorta, A., Turchetta, S., Bovicelli, P., Botta, M. (1991). SYNTHESIS OF SUBSTITUTED CIS-BICYCLO[3.3.0]OCTANE-1-CARBONYL DERIVATIVES BY STEREOSPECIFIC REARRANGEMENT OF 1-CHLORO-9-HYDROXYBICYCLO-[3.3.1]NONANES. TETRAHEDRON, 47(43), 9097-9102 [10.1016/S0040-4020(01)86512-1].
SYNTHESIS OF SUBSTITUTED CIS-BICYCLO[3.3.0]OCTANE-1-CARBONYL DERIVATIVES BY STEREOSPECIFIC REARRANGEMENT OF 1-CHLORO-9-HYDROXYBICYCLO-[3.3.1]NONANES
GAMBACORTA, Augusto;
1991-01-01
Abstract
Substituted cis-1-formyl (or acetyl) bicyclo[3.3.0]octanes are stereospecifically obtained in high yield by a base-catalyzed rearrangement of readily accessible substituted 1-chloro-9-hydroxy (or acetoxy) bicyclo[3.3.1] nonanes.File in questo prodotto:
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