Benvenuti nell'Anagrafe della Ricerca d'Ateneo
La valutazione delle attività di ricerca che si svolgono nelle università ha assunto un'importanza rilevante sia per l'intero sistema universitario sia all'interno di ogni singolo ateneo. Roma Tre si è quindi dotata di idonei strumenti informativi in grado di supportare al meglio le azioni di monitoraggio e di valutazione delle attività di ricerca svolte nei propri dipartimentied ha realizzato una Anagrafe della Ricerca di Ateneo.
EnglishWe present a molecular-dynamics study of the self-dynamics of water molecules in deeply supercooled liquid states. We find that the decay of single-particle dynamics correlation functions is characterized by a fast initial relaxation toward a plateau and by a region of self-similar dynamics, followed at late times by a stretched exponential decay. We interpret such results in the framework of the mode-coupling theory for supercooled liquids. We relate the apparent anomalies of the transport coefficients in water on lowering the temperature to the formation of cages and to the associated slow dynamics resulting from the presence of long-lived molecular cages. The so-called critical Angell temperature in supercooled water could thus be interpreted as kinetic glass transition temperature, relaxing the need of a thermodynamic singularity for the explanation of the anomalies of Liquid water.
Sciortino F, Gallo P, Tartaglia P, & Chen SH (1996). Supercooled water and the kinetic glass transition. PHYSICAL REVIEW E, 54(6), 6331-6343 [10.1103/PhysRevE.54.6331].
| Titolo: | Supercooled water and the kinetic glass transition | |
| Autori: | ||
| Data di pubblicazione: | 1996 | |
| Rivista: | ||
| Citazione: | Sciortino F, Gallo P, Tartaglia P, & Chen SH (1996). Supercooled water and the kinetic glass transition. PHYSICAL REVIEW E, 54(6), 6331-6343 [10.1103/PhysRevE.54.6331]. | |
| Abstract: | We present a molecular-dynamics study of the self-dynamics of water molecules in deeply supercooled liquid states. We find that the decay of single-particle dynamics correlation functions is characterized by a fast initial relaxation toward a plateau and by a region of self-similar dynamics, followed at late times by a stretched exponential decay. We interpret such results in the framework of the mode-coupling theory for supercooled liquids. We relate the apparent anomalies of the transport coefficients in water on lowering the temperature to the formation of cages and to the associated slow dynamics resulting from the presence of long-lived molecular cages. The so-called critical Angell temperature in supercooled water could thus be interpreted as kinetic glass transition temperature, relaxing the need of a thermodynamic singularity for the explanation of the anomalies of Liquid water. | |
| Handle: | http://hdl.handle.net/11590/131565 | |
| Appare nelle tipologie: | 1.1 Articolo in rivista |
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