PEP and aldolase mimicry is the key for a direct organocatalytic entry to precursors of ulosonic acids, biomolecules of enormous importance in biology, chemistry and medicine; in the key aldol reaction the dimethylacetal of pyruvic aldehyde is used as phosphoenolpyruvate (PEP) equivalent and the amino acid proline functions as an organocatalyst, imitating the enzyme
ENDERS D, & GASPERI T (2007). Proline organocatalysis as a new tool for the asymmetric synthesis of ulosonic acid precursors. CHEMICAL COMMUNICATIONS(1), 88-90.
Titolo: | Proline organocatalysis as a new tool for the asymmetric synthesis of ulosonic acid precursors |
Autori: | |
Data di pubblicazione: | 2007 |
Rivista: | |
Citazione: | ENDERS D, & GASPERI T (2007). Proline organocatalysis as a new tool for the asymmetric synthesis of ulosonic acid precursors. CHEMICAL COMMUNICATIONS(1), 88-90. |
Abstract: | PEP and aldolase mimicry is the key for a direct organocatalytic entry to precursors of ulosonic acids, biomolecules of enormous importance in biology, chemistry and medicine; in the key aldol reaction the dimethylacetal of pyruvic aldehyde is used as phosphoenolpyruvate (PEP) equivalent and the amino acid proline functions as an organocatalyst, imitating the enzyme |
Handle: | http://hdl.handle.net/11590/141509 |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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