3-(Phosphorylmethylene)oxindoles have been prepared by a straightforward Horner-Wadsworth-Emmons reaction. They were treated with ethyl N-{[(4-nitrophenyl)sulfonyl]oxy}-carbamate (NsONHCO(2)Et) in the presence of CaO to afford new aziridine-2-phosphonates spiro-fused with oxindole. 3(Phosphorylmethylene)oxindoles were also transformed into novel spiro[oxindole-oxiranes] by reaction with H(2)O(2)/NaOH.

Gasperi, T., Loreto M., A., Migliorini, A., Ventura, C. (2011). Synthesis of Aziridine- and Oxirane-2-phosphonates Spiro-Fused with Oxindoles. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(2), 385-391 [10.1002/ejoc.201001021].

Synthesis of Aziridine- and Oxirane-2-phosphonates Spiro-Fused with Oxindoles

GASPERI, TECLA;
2011-01-01

Abstract

3-(Phosphorylmethylene)oxindoles have been prepared by a straightforward Horner-Wadsworth-Emmons reaction. They were treated with ethyl N-{[(4-nitrophenyl)sulfonyl]oxy}-carbamate (NsONHCO(2)Et) in the presence of CaO to afford new aziridine-2-phosphonates spiro-fused with oxindole. 3(Phosphorylmethylene)oxindoles were also transformed into novel spiro[oxindole-oxiranes] by reaction with H(2)O(2)/NaOH.
2011
Gasperi, T., Loreto M., A., Migliorini, A., Ventura, C. (2011). Synthesis of Aziridine- and Oxirane-2-phosphonates Spiro-Fused with Oxindoles. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY(2), 385-391 [10.1002/ejoc.201001021].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11590/155406
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