Sr2FeMoO6 double perovskits display low field MR at a relatively high temperature and unusual ferromagnetic properties. These compounds depicts metal to insulator transition increasing x above xc ~ 0.25. A comparative analysis of the near edge regions (XANES) suggests that iron is Fe3+ in the metallic range. Checking the end compounds, we found that the doped samples can be viewn as inhomogeneous distributions of the end compounds. This could help to distinguish between the two scenarios proposed to explain the metal to insulator transition. Moreover, the local atomic structure of Sr2FeMoxW1−xO6 as a function of composition (0 ≤ x ≤ 1) has been investigated by Extended x-ray absorption spectroscopy (EXAFS) a the Fe, Mo, Sr K-edges and W LIII-edge.
F., B., Meneghini, C., Mobilio, S., Sugata, R., D. D., S. (2005). Local Structure of Sr2FeMox W1xO6 Double Perovskites Studied by EXAFS. PHYSICA SCRIPTA, T115, 457-459.
Local Structure of Sr2FeMox W1xO6 Double Perovskites Studied by EXAFS
MENEGHINI, CARLO;MOBILIO, Settimio;
2005-01-01
Abstract
Sr2FeMoO6 double perovskits display low field MR at a relatively high temperature and unusual ferromagnetic properties. These compounds depicts metal to insulator transition increasing x above xc ~ 0.25. A comparative analysis of the near edge regions (XANES) suggests that iron is Fe3+ in the metallic range. Checking the end compounds, we found that the doped samples can be viewn as inhomogeneous distributions of the end compounds. This could help to distinguish between the two scenarios proposed to explain the metal to insulator transition. Moreover, the local atomic structure of Sr2FeMoxW1−xO6 as a function of composition (0 ≤ x ≤ 1) has been investigated by Extended x-ray absorption spectroscopy (EXAFS) a the Fe, Mo, Sr K-edges and W LIII-edge.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
