This work reports the synthesis and crystal-chemistry of ferri-clinoferroholmquistite in the system Li(2)O - FeO - Fe(2)O(3) - SiO(2) - H(2)O. Ferri-clinoferroholmquistite has a very restricted temperature stability. An almost monophase amphibole product is obtained at 500degreesC for a wide pressure range (1-7 kbar), whereas a Li-bearing pyroxene becomes predominant for T greater than or equal to 600degreesC. The X-ray powder pattern of ferri-clinoferroholmquistite was indexed in the C2/m space group. Refined cell dimensions are: a = 9.489 (2), b = 18.036 (7), c = 5.313 (3) Angstrom; beta = 101.59 (3). Infrared spectra in the OH-stretching region show the presence of a single and very sharp band at 3614 cm(-1), which is assigned to the Fe(2+)Fe(2+)Fe(2+) trimer at the OH-coordinated M1M1M3 octahedra, and a small satellite band at 3644 cm(-1) which was assigned to Li at M3. Mossbauer spectra can be fitted to three doublets assigned to Fe(3+) at M2, Fe(2+) at M1 and Fe(2+) at M3, respectively, with a calculated Fe(2+)/Fe(2+) ratio of 2/3, suggesting a composition close to the nominal one. The spectroscopic data show that synthetic ferri-clinoferroholmquistite has a strongly ordered cation distribution, in agreement with single-crystal refinements done by Caballero et al. (1998) and Oberti et al. (2000) on natural samples with related Li-rich compositions.
Iezzi, G., DELLA VENTURA, G., Pedrazzi, G., Robert, ., J. L. E., O. (2003). Synthesis and characterisation of ferri-clinoferroholmquistite, οLi2(Fe2+3Fe3+2)Si8O22(OH)2. EUROPEAN JOURNAL OF MINERALOGY, 15, 321-327 [10.1127/0935-1221/2003/0015-0321].
Synthesis and characterisation of ferri-clinoferroholmquistite, οLi2(Fe2+3Fe3+2)Si8O22(OH)2
DELLA VENTURA, Giancarlo;
2003-01-01
Abstract
This work reports the synthesis and crystal-chemistry of ferri-clinoferroholmquistite in the system Li(2)O - FeO - Fe(2)O(3) - SiO(2) - H(2)O. Ferri-clinoferroholmquistite has a very restricted temperature stability. An almost monophase amphibole product is obtained at 500degreesC for a wide pressure range (1-7 kbar), whereas a Li-bearing pyroxene becomes predominant for T greater than or equal to 600degreesC. The X-ray powder pattern of ferri-clinoferroholmquistite was indexed in the C2/m space group. Refined cell dimensions are: a = 9.489 (2), b = 18.036 (7), c = 5.313 (3) Angstrom; beta = 101.59 (3). Infrared spectra in the OH-stretching region show the presence of a single and very sharp band at 3614 cm(-1), which is assigned to the Fe(2+)Fe(2+)Fe(2+) trimer at the OH-coordinated M1M1M3 octahedra, and a small satellite band at 3644 cm(-1) which was assigned to Li at M3. Mossbauer spectra can be fitted to three doublets assigned to Fe(3+) at M2, Fe(2+) at M1 and Fe(2+) at M3, respectively, with a calculated Fe(2+)/Fe(2+) ratio of 2/3, suggesting a composition close to the nominal one. The spectroscopic data show that synthetic ferri-clinoferroholmquistite has a strongly ordered cation distribution, in agreement with single-crystal refinements done by Caballero et al. (1998) and Oberti et al. (2000) on natural samples with related Li-rich compositions.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.