The use of palladium nanoparticles stabilized by natural. beads made of an alginate/gellan mixture in the Suzuki-Miyaura cross-coupling reaction of arenediazonium. tetrafluoroborates with potassium aryltrifluoroborates. (1 : 1 molar ratio) with loading as low as 0.01–0.002. mol% under aerobic, phosphine-, and base-free conditions. in water is described. The catalyst system can be reused. several times without significant loss of activity.

Cacchi, S., Caponetti, E., Casadei, M.a., DI GIULIO, A., Fabrizi, G., Forte, G., et al. (2012). Suzuki-Miyaura cross-coupling of arenediazonium salts catalyzed by alginate/gellan-stabilized palladium nanoparticles under aerobic conditions in water. GREEN CHEMISTRY, 14(2), 317-320 [10.1039/c2gc15679b].

Suzuki-Miyaura cross-coupling of arenediazonium salts catalyzed by alginate/gellan-stabilized palladium nanoparticles under aerobic conditions in water

DI GIULIO, ANDREA;MORENO, Sandra;
2012-01-01

Abstract

The use of palladium nanoparticles stabilized by natural. beads made of an alginate/gellan mixture in the Suzuki-Miyaura cross-coupling reaction of arenediazonium. tetrafluoroborates with potassium aryltrifluoroborates. (1 : 1 molar ratio) with loading as low as 0.01–0.002. mol% under aerobic, phosphine-, and base-free conditions. in water is described. The catalyst system can be reused. several times without significant loss of activity.
Cacchi, S., Caponetti, E., Casadei, M.a., DI GIULIO, A., Fabrizi, G., Forte, G., et al. (2012). Suzuki-Miyaura cross-coupling of arenediazonium salts catalyzed by alginate/gellan-stabilized palladium nanoparticles under aerobic conditions in water. GREEN CHEMISTRY, 14(2), 317-320 [10.1039/c2gc15679b].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11590/278582
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