"""""""A novel asymmetric nucleophilic epoxidation for R-ylideneoxindole esters has been successfully devised, resulting in enantioenriched spiro compounds with two new contiguous stereocenters. The employed (S)-R,R-diphenylprolinol functions as a bifunctional catalyst, creating a complex H-bond network in conjunction with a substrate and an oxidant"""""""
GASPERI T, TOFANI D, GAMBACORTA A, PALUMBO C, MAZZEO G, MAZZIOTTA A, et al. (2011). Noncovalent Organocatalysis: A Powerful Tool for the Nucleophilic Epoxidation of α-Ylideneoxindoles. ORGANIC LETTERS, 13(23), 6248-6251 [10.1021/ol202646w].
Titolo: | Noncovalent Organocatalysis: A Powerful Tool for the Nucleophilic Epoxidation of α-Ylideneoxindoles | |
Autori: | ||
Data di pubblicazione: | 2011 | |
Rivista: | ||
Citazione: | GASPERI T, TOFANI D, GAMBACORTA A, PALUMBO C, MAZZEO G, MAZZIOTTA A, et al. (2011). Noncovalent Organocatalysis: A Powerful Tool for the Nucleophilic Epoxidation of α-Ylideneoxindoles. ORGANIC LETTERS, 13(23), 6248-6251 [10.1021/ol202646w]. | |
Abstract: | """""""A novel asymmetric nucleophilic epoxidation for R-ylideneoxindole esters has been successfully devised, resulting in enantioenriched spiro compounds with two new contiguous stereocenters. The employed (S)-R,R-diphenylprolinol functions as a bifunctional catalyst, creating a complex H-bond network in conjunction with a substrate and an oxidant""""""" | |
Handle: | http://hdl.handle.net/11590/278767 | |
Appare nelle tipologie: | 1.1 Articolo in rivista |
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