Subsurface seepage dynamics and flow types in a Messinian paleoseep system (Maiella Mts., Central Italy)

The subsurface feeder complexes of mud volcanoes and seepage systems potentially provide valuable information on the evolution of seepage dynamics. Ancient seepage systems in outcrops allow for the observation of expulsion features, which are otherwise commonly beyond seismic resolution. In the Maiella hydrocarbon seep area, the evolution of fluid migration through the sedimentary column during the Messinian Salinity Crisis generated distinctive seep-plumbing features, geological responses, and geochemical signatures in the “Brecciated Limestones” unit. The fluid migration pathways evolved from funnel-shaped feeder channels (Flow-mobilized Sediments) into hydrofractured microbial carbonate buildups (Limestone Buildups), and finally into blow-out micropipes in the host sediment (Patchy Limestones), as overpressure dissipated through the plumbing system. The Flow-mobilized Sediments (δ13C down to − 24.5‰ PDB-1) correspond to the highest flow rates in the whole area, whereas the Patchy Limestones (δ13C down to − 39.3‰ PDB-1) correspond to the slowest flow rates within the intrusive zone. The Limestone Buildups show different degrees of hydrofracturing that reflect different flow rates (δ13C down to − 27.5‰ PDB-1). The fluid transport mechanisms evolved from focused venting through neoformed feeder channels, where sediments elutriated from depths were carried out (the sediment-prone response to fluid migration), to high-rate seepage triggering high hydrofracturation in the microbial buildups. While the hydrocarbon-rich fluids contemporaneously triggered authigenic precipitation (the mineral-prone response to fluid migration), progressive upward and lateral flow deceleration resulted in gradually weaker hydrofracturing of the microbial buildups and finally only local cementation in the form of carbonate patches within the host sediments.