The high sintering temperature of Yttrium doped barium zirconate (BZY), the most promising high temperature proton conductor (HTPC) for Intermediate Temperature (400-750 °C) Solid Oxide Fuel Cells (IT-SOFCs), has been reduced by using ZnO as a sintering aid. Obtaining a dense electrolyte at a reduced temperature allows conventional fuel cell preparation methods. A reproducible spin coating method to fabricate highly performing anode supported button cells with dense micrometric BZYZn electrolyte layers has been developed. The electrochemical characterization of button cells at 600 °C shows promising performance, higher than that of comparable fuel cells from literature. © 2012 Elsevier B.V. All rights reserved.
Luisetto, I., Licoccia, S., D'Epifanio, A., Sanson, A., Mercadelli, E., Di Bartolomeo, E. (2012). Electrochemical performance of spin coated dense BaZr 0.80Y 0.16Zn 0.04O 3-δ membranes. JOURNAL OF POWER SOURCES, 220, 280-285 [10.1016/j.jpowsour.2012.07.136].
Electrochemical performance of spin coated dense BaZr 0.80Y 0.16Zn 0.04O 3-δ membranes
LUISETTO, IGOR;
2012-01-01
Abstract
The high sintering temperature of Yttrium doped barium zirconate (BZY), the most promising high temperature proton conductor (HTPC) for Intermediate Temperature (400-750 °C) Solid Oxide Fuel Cells (IT-SOFCs), has been reduced by using ZnO as a sintering aid. Obtaining a dense electrolyte at a reduced temperature allows conventional fuel cell preparation methods. A reproducible spin coating method to fabricate highly performing anode supported button cells with dense micrometric BZYZn electrolyte layers has been developed. The electrochemical characterization of button cells at 600 °C shows promising performance, higher than that of comparable fuel cells from literature. © 2012 Elsevier B.V. All rights reserved.I documenti in IRIS sono protetti da copyright e tutti i diritti sono riservati, salvo diversa indicazione.
