The Interaction Between Groundwater and Surface Water in the Southern Sector of the Sabatini Mountains Hydrogeological Structure (Central Italy) Using a Comprehensive Hydrogeological and Geochemical Approach

Groundwater-surface water interactions in volcanic hydrogeological systems represent a key process in river dynamics and were preliminarily investigated along a river draining the southern sector of the Sabatini Mountains (central Italy) using an integrated hydrogeological and geochemical approach. Serial discharge measurements, combined with physico-chemical parameters, major ions, stable oxygen isotopes, and radon analyses, reveal marked spatial variability in river-aquifer exchanges along distinct river reaches. The Arrone River exhibits clear differences between upstream, intermediate, and downstream sections, reflecting the relative influence of localized anthropogenic inputs, diffuse groundwater discharge from the volcanic aquifer, and subsurface flow contributions. Upstream reaches are characterized by pronounced modifications in discharge and chemistry, whereas intermediate and downstream reaches show progressive groundwater influence, resulting in distinct geochemical signatures and changes in water quality. Correlation and cluster analyses identify reach-specific processes controlling water composition and support the recognition of gaining and mixed river conditions under varying hydrological regimes. These results constrain a conceptual model in which river behavior is governed by spatially heterogeneous groundwater inflows, modulated by seasonal discharge dynamics and local human pressures. This study highlights the importance of reach-scale investigations for understanding SW-GW interactions in volcanic settings and provides transferable insights relevant to groundwater-dependent river systems.