We present the nanoheteroepitaxial growth of gallium arsenide (GaAs) on nano-patterned silicon (Si) (001) substrates fabricated using a CMOS technology compatible process. The selective growth of GaAs nano-crystals (NCs) was achieved at 570 °C by MOVPE. A detailed structure and defect characterization study of the grown nano-heterostructures was performed using scanning transmission electron microscopy, x-ray diffraction, micro-Raman, and micro-photoluminescence (μ-PL) spectroscopy. The results show single-crystalline, nearly relaxed GaAs NCs on top of slightly, by the SiO2-mask compressively strained Si nano-tips (NTs). Given the limited contact area, GaAs/Si nanostructures benefit from limited intermixing in contrast to planar GaAs films on Si. Even though a few growth defects (e.g. stacking faults, micro/nano-twins, etc) especially located at the GaAs/Si interface region were detected, the nanoheterostructures show intensive light emission, as investigated by μ-PL spectroscopy. Achieving well-ordered high quality GaAs NCs on Si NTs may provide opportunities for superior electronic, photonic, or photovoltaic device performances integrated on the silicon technology platform.

Skibitzki, O., Prieto, I., Kozak, R., Capellini, G., Zaumseil, P., Arroyo Rojas Dasilva, Y., et al. (2017). Structural and optical characterization of GaAs nano-crystals selectively grown on Si nano-tips by MOVPE. NANOTECHNOLOGY, 28(13), 135301 [10.1088/1361-6528/aa5ec1].

Structural and optical characterization of GaAs nano-crystals selectively grown on Si nano-tips by MOVPE

CAPELLINI, GIOVANNI;
2017-01-01

Abstract

We present the nanoheteroepitaxial growth of gallium arsenide (GaAs) on nano-patterned silicon (Si) (001) substrates fabricated using a CMOS technology compatible process. The selective growth of GaAs nano-crystals (NCs) was achieved at 570 °C by MOVPE. A detailed structure and defect characterization study of the grown nano-heterostructures was performed using scanning transmission electron microscopy, x-ray diffraction, micro-Raman, and micro-photoluminescence (μ-PL) spectroscopy. The results show single-crystalline, nearly relaxed GaAs NCs on top of slightly, by the SiO2-mask compressively strained Si nano-tips (NTs). Given the limited contact area, GaAs/Si nanostructures benefit from limited intermixing in contrast to planar GaAs films on Si. Even though a few growth defects (e.g. stacking faults, micro/nano-twins, etc) especially located at the GaAs/Si interface region were detected, the nanoheterostructures show intensive light emission, as investigated by μ-PL spectroscopy. Achieving well-ordered high quality GaAs NCs on Si NTs may provide opportunities for superior electronic, photonic, or photovoltaic device performances integrated on the silicon technology platform.
Skibitzki, O., Prieto, I., Kozak, R., Capellini, G., Zaumseil, P., Arroyo Rojas Dasilva, Y., et al. (2017). Structural and optical characterization of GaAs nano-crystals selectively grown on Si nano-tips by MOVPE. NANOTECHNOLOGY, 28(13), 135301 [10.1088/1361-6528/aa5ec1].
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Utilizza questo identificativo per citare o creare un link a questo documento: https://hdl.handle.net/11590/315537
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